I'm pretty sure everything has an internal cooldown, including monster helms. As Omnidevil mentioned, it's easiest to gauge these internal CDs when stated directly or implied by specific time frames in the tooltip. But this doesn't mean that something that doesn't specify doesn't have a cooldown.

Take the Maw of the Infernal set piece, for example. the more obvious portion of the internal CD lies within the concept that only one daedroth can be active at a time, which in essence means it has at least an internal CD of 15 seconds. But there is still an internal cooldown to everything, and even the CD on the daedroth may be longer than 15 seconds. In some cases it may be negligible.

To illustrate, imagine there being a delay between the first daedroth expiring and the first opportunity that the 2nd can spawn. This delay might be something as minuscule as 0.1 sec, but this is inherent to just about everything in ESO. Even instant-cast skills have an internal CD, meaning that there is a delay (albeit negligible) between when the first cast completes and the opportunity for the second to be cast.

This is, in part, why animation cancelling makes weaving skills together more efficient. Cooldowns operate independently from animations. No matter how much of the animation one may shave off of a particular skill, it still cannot be cast before the cooldown expires - even if this cooldown is incredibly short.

Engine Guardian should have a internal cool down. That thing is so broken.

As far as Engine Guardian and Nerien'ths I think they have a very short cooldown.

You cant proc the effect while the effect is active but you can proc it right after the effect has ended.

Thanks for all your input guys. Mixed answers regarding the EG. As long as my EG set carries on proccing as much as it does then I'm good haha.

Yeah seems to proc quite often. Not always the one I need though (magicka mostly) but the extra stamina it gives helps with blocking/breakfree costs and extra health is always welcome.