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yeah there is no way to cast both of those skills at the same time
however if you were using sheer venom set, poison injection, and either of those, all 3 have independently calculated execute dmg that would work at the same time
i have my main house (grand topal hideaway) listed in the housing tours, it has multiple target dummies, scribing altar, and grandmaster stations (in progress being filled out), as well as almost every antiquity furnishing on display to preview them
Multiple people can execute a target at the same time, yes.
Your inquiry makes more sense if you're trying to cast both because you missed the part where Radiant Destruction and its morphs are a channeled ability.
I am not sure what you mean by "stack". Both do damage based on enemy health. The damage they do is independent of each other and only based on enemy health. I don't see anything to "stack".
When you deal damage with an Execute ability you infect the enemy, dealing 948 Poison damage over 6 seconds and dealing up to 100% more damage to enemies under 100% Health. This effect can occur once every 6 seconds per target and scales off the higher of your Weapon or Spell Damage.
So both would proc this yes? And ya....I was wrong on my "stack" thinking that's for point that out.