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I had a thought that just occurred to me when I was thinking of set combos to go with a healer.. With the Physician set effect to grant those you crit heal with a damage shield, would that in turn proc the Trinimac set effect?
I had thought of this combination as well back when Orsinium released. Pretty sure it's one of those combinations that sound great but won't actually perform as you want though
By all means, if you gather the pieces you should really give it a try. I have doubts I could gather them to test for you but hopefully someone can in the DB patch and give guaranteed Yes or No results.